Non-LTE Radiative Transfer in the Atmosphere

Ch. 1. Introduction and overview. 1.1. General introduction. 1.2. Basic properties of the Earth's atmosphere. 1.3. What is LTE? 1.4. Non-LTE situations. 1.5. The importance of non-LTE. 1.6. Some historical background. 1.7. Non-LTE models. 1.8. Experimental studies of non-LTE. 1.9. Non-LTE in planetary atmospheres. 1.10. References and further reading -- ch. 2. Molecular spectra. 2.1. Introduction. 2.2. Energy levels in diatomic molecules. 2.3. Energy levels in polyatomic molecules. 2.4. Transitions and spectral bands. 2.5. Properties of individual vibration-rotation lines. 2.6. Interactions between energy levels. 2.7. References and further reading -- ch. 3. Basic atmospheric radiative transfer. 3.1. Introduction. 3.2. Properties of radiation. 3.3. The radiative transfer equation. 3.4. The formal solution of the radiative transfer equation. 3.5. Thermodynamic equilibrium and local thermodynamic equilibrium. 3.6. The source function in non-LTE. 3.7. Non-LTE situations. 3.8. References and further reading -- ch. 4. Solutions to the radiative transfer equation in LTE. 4.1. Introduction. 4.2. Integration of the radiative transfer equation over height. 4.3. Integration of the radiative transfer equation over frequency. 4.4. Integration of the radiative transfer equation over solid angle. 4.5. References and further reading -- ch. 5. Solutions to the radiative transfer equation in non-LTE. 5.1. Introduction. 5.2. Simple solutions for radiative transfer under non-LTE. 5.3. The full solution of the radiative transfer equation in non-LTE. 5.4. Integration of the RTE in non-LTE. 5.5. Intercomparison of non-LTE codes. 5.6. Parameterizations of the non-LTE cooling rate. 5.7. The Curtis matrix method. 5.8. References and further reading -- ch. 6. Non-LTE modelling of the Earth's atmosphere I: CO2. 6.1. Introduction. 6.2. Useful approximations. 6.3. Carbon dioxide, CO2. 6.4. References and further reading -- ch. 7. Non-LTE modelling of the Earth's atmosphere II: Other infrared emitters. 7.1. Introduction. 7.2. Carbon monoxide, CO. 7.3. Ozone, O3. 7.4. Water vapour, H2O. 7.5. Methane, CH4. 7.6. Nitric oxide, NO. 7.7. Nitrogen dioxide, NO2. 7.8. Nitrous oxide, N2O. 7.9. Nitric acid, HNO3. 7.10. Hydroxyl radical, OH. 7.11. Molecular oxygen atmospheric infrared bands. 7.12. Hydrogen chloride, HC1, and hydrogen fluoride, HF. 7.13. NO+. 7.14. Atomic Oxygen, O (3P), at 63[symbol]m. 7.15. References and further reading -- ch. 8. Remote sensing of the non-LTE atmosphere. 8.1. Introduction. 8.2. The analysis of emission measurements. 8.3. Observations of carbon dioxide in emission. 8.4. Observations of ozone in emission. 8.5. Observations of water vapour in emission. 8.6. Observations of carbon monoxide in emission. 8.7. Observations of nitric oxide in emission. 8.8. Observations of other infrared emissions. 8.9. Rotational non-LTE. 8.10. Absorption measurements. 8.11. Simulated limb emission spectra at high resolution. 8.12. Simulated Nadir emission spectra at high resolution. 8.13. Non-LTE retrieval schemes. 8.14. References and further reading -- ch. 9. Cooling and heating rates. 9.1. Introduction. 9.2. CO2 15 f[symbol]m cooling. 9.3. O3 9.6[symbol]xm cooling. 9.4. H2O 6.3[symbol]m cooling. 9.5. NO 5.3[symbol]m cooling. 9.6. O(3Pi) 63[symbol]m cooling. 9.7. Summary of cooling rates. 9.8. CO2 solar heating. 9.9. References and further reading -- ch. 10. Non-LTE in planetary atmospheres. 10.1. Introduction. 10.2. The terrestrial planets: Mars and Venus. 10.3. A non-LTE model for the Martian and Venusian atmospheres. 10.4. Mars. 10.5. Venus. 10.6. Outer planets. 10.7. Titan. 10.8. Comets. 10.9. References and further reading.