Properties of Single Organic Molecules on Crystal Surfaces

Within nanoscience, an emerging discipline is the study of the physics and chemistry of single molecules. Molecules may be considered as the ultimate building blocks, and are therefore interesting for the development of molecular devices and for surface functionalization. Thus, it is interesting to study their properties when adsorbed on a suitable substrate such as a solid or crystal surface, and also for their potential applications in nano- or molecular-electronics and nanosensing. Investigations have been made possible by the advent of high resolution surface imaging and characterization techniques, commonly referred to as Scanning Probe Microscopes. This book focuses on the fascinating properties of the single molecules, and the difference between single molecules and ensembles of molecules is emphasized. As the first book intended for graduate courses in the field, after each chapter, students should be able to answer the question: “What physical or chemical properties do you learn from a single molecule in this particular context?” Contributed by experts across the disciplines, the book provides useful reference material for specialized practitioners in surface science, nanoscience and nanoelectronics. Contents:Introduction:Basic Properties of Metal Surfaces (A L Vázquez de Parga & R Miranda)Basic Properties of Silicon Surfaces (M J Butcher & M Y Simmons)Experimental Methods:Scanning Tunneling Microscopy and Scanning Force Microscopy (S Hembacher & F Giessibl)Optical Detection of Single Molecules at Interfaces (B Hecht)Theoretical Methods:Ab Initio Modeling of Molecular Electronics (D Roubtsov et al.)Perturbation Methods in Scanning Tunneling Microscopy (W A Hofer)Spectroscopy of Single Molecule(s) on Surfaces:Properties of Single Molecules: Manipulation, Dissociation and Synthesis with the Scanning Tunneling Microscope (K-F Braun & S-W Hla)Single Molecule Vibrational Spectroscopy and Chemistry (J I Pascual & N Lorente)Local Modification of Surfaces Induced by Adsorbed Molecules:Superlattices of Atoms, Molecules and Islands (H Brune)Mobility of Complex Organic Species at Metal Surfaces (J V Barth)Molecular Monolayers on Silicon Surfaces (G P Lopinski & D D M Wayner)Functionalization of Semiconductor Surfaces by Organic Layers: Concerted Cycloaddition versus Stepwise Free-Radical Reaction Mechanisms (A Bilic et al.)Electronic Properties of Single Molecules on Metal Surfaces:Molecular Electronics (R Stadler)Exploring the Catalytic Activity of a Noble Metal: The Ag Catalyzed Ethylene Epoxidation Reaction (M-L Bocquet & A Michaelides) Readership: Graduate students, scientists, researchers in condensed matter physics, physical chemistry, materials and nanoscience. Keywords:Nanoscience;Molecular Electronics;Scanning Probe Microscopy;Molecule-Surface InteractionsKey Features:Each chapter is self-contained and written in a readable style, accessible to a broad audience of non-specialistsAll chapters have been peer-reviewedReviews:“On the whole, the book offers some outstanding reviews of single molecule research in the past decade with a particular emphasis on scanning tunneling microscopy.”Journal of the American Chemical Society “I found all of the articles to be of real interest and to contain information that broadened my existing knowledge. The articles were also helpful in not only presenting current research, but in providing critical comment and highlighting areas for future work. I was also impressed by the balance between experiment and theory … I believe that this book would be a very valuable text for graduate students, teachers and researchers interested in the interaction of organic molecules with surfaces.”Australian Physics